Journal article

Characterization of Alkanes and α-Olefins from the Thermo-Chemical Conversion of Animal Fat


Authors listWeber, Bernd; Stadlbauer, Ernst A.; Eichenauer, Sabrina; Frank, Andreas; Steffens, Diedrich; Schlich, Elmar; Schilling, Gerhard

Publication year2014

Pages526-537

JournalJournal of Biobased Materials and Bioenergy

Volume number8

Issue number5

ISSN1556-6560

eISSN1556-6579

DOI Linkhttps://doi.org/10.1166/jbmb.2014.1464

PublisherAmerican Scientific Publishers


Abstract
Lipids are important raw materials for chemical industry, food industry and cosmetics. In the context of replacing fossil resources, lipids are gaining considerable attention as sustainable feedstock for fuels and value-added chemicals. This study focuses on the composition of products obtained from the thermo-chemical conversion of animal fat in a moving bed of sodium carbonate at 430 degrees C in the presence of water. Their chemical nature is determined by Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance spectroscopy (H-1 NMR), carbon nuclear magnetic resonance spectroscopy (C-13 NMR), chromatography and mass spectroscopy. The primary components of the bio-crude are a homologous series of straight chain alkanes and alkenes composed mostly of terminal double bonds. Fractionated distillation of the bio-crude yields a hydrocarbon-based biodiesel. Its characteristics comply with nearly all parameters of European diesel fuel standards. Thus, it can be used in internal combustion engines. The gasoline fraction exhibits a quality comparable to that of straight run fractions from fossil fuel processing. Moreover, with 18 mg/g methyl heptadecyl ketone is the primary polar component of bio-crude.



Citation Styles

Harvard Citation styleWeber, B., Stadlbauer, E., Eichenauer, S., Frank, A., Steffens, D., Schlich, E., et al. (2014) Characterization of Alkanes and α-Olefins from the Thermo-Chemical Conversion of Animal Fat, Journal of Biobased Materials and Bioenergy, 8(5), pp. 526-537. https://doi.org/10.1166/jbmb.2014.1464

APA Citation styleWeber, B., Stadlbauer, E., Eichenauer, S., Frank, A., Steffens, D., Schlich, E., & Schilling, G. (2014). Characterization of Alkanes and α-Olefins from the Thermo-Chemical Conversion of Animal Fat. Journal of Biobased Materials and Bioenergy. 8(5), 526-537. https://doi.org/10.1166/jbmb.2014.1464



Keywords


Aliphatic HydrocarbonsCANOLA OILCATALYTIC CRACKINGDIESEL-LIKE FUELGASOLINEH-1-NMR SPECTROSCOPYSodium CarbonateSODIUM-CARBONATEThermal DegradationVEGETABLE-OILS

Last updated on 2025-02-04 at 02:07