Journalartikel

Climbing up the vibrational ladder of HC15N: High-temperature near-infrared emission measurements


AutorenlistePredoi-Cross, A.; Johnson, E.; Hemsing, D.; Rozario, H.; Mellau, Georg Ch

Jahr der Veröffentlichung2013

Seiten27-32

ZeitschriftJournal of Molecular Spectroscopy

Bandnummer293

ISSN0022-2852

eISSN1096-083X

DOI Linkhttps://doi.org/10.1016/j.jms.2013.10.002

VerlagElsevier


Abstract
The near-infrared (NIR) emission spectrum of (HCN)-C-12-N-15 was measured in the 6050-6500 cm(-1) range at a resolution of 0.044 cm(-1) using an emission setup available at the Justus-Liebig Universitat, Giessen, Germany. The rich emission spectrum showing numerous overlapped spectral profiles was analyzed with the spectrum analysis software SyMath running using Mathematica as a platform. This approach allowed us to retrieve the vibrational-rotational constants for 32 bands. Many spectroscopic transitions have been observed for the first time in a lab environment. We quantified four newly observed Coriolis resonances. (C) 2013 Elsevier Inc. All rights reserved.



Autoren/Herausgeber




Zitierstile

Harvard-ZitierstilPredoi-Cross, A., Johnson, E., Hemsing, D., Rozario, H. and Mellau, G. (2013) Climbing up the vibrational ladder of HC15N: High-temperature near-infrared emission measurements, Journal of Molecular Spectroscopy, 293, pp. 27-32. https://doi.org/10.1016/j.jms.2013.10.002

APA-ZitierstilPredoi-Cross, A., Johnson, E., Hemsing, D., Rozario, H., & Mellau, G. (2013). Climbing up the vibrational ladder of HC15N: High-temperature near-infrared emission measurements. Journal of Molecular Spectroscopy. 293, 27-32. https://doi.org/10.1016/j.jms.2013.10.002



Schlagwörter


ATMOSPHEREBending vibrationsEmission spectraHCN(HCN)-C-12-N-15(HCN)-N-15HNCMolecular spectraNU(1) BAND SYSTEMRovibrational constants


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