Journalartikel

Long-Term Lysimeter Experiment To Investigate the Leaching of Perfluoroalkyl Substances (PFASs) and the Carry-over from Soil to Plants: Results of a Pilot Study


AutorenlisteStahl, Thorsten; Riebe, Rika Alessa; Falk, Sandy; Failing, Klaus; Brunn, Hubertus

Jahr der Veröffentlichung2013

Seiten1784-1793

ZeitschriftJournal of Agricultural and Food Chemistry

Bandnummer61

Heftnummer8

ISSN0021-8561

eISSN1520-5118

DOI Linkhttps://doi.org/10.1021/jf305003h

VerlagAmerican Chemical Society


Abstract
To study the behavior of perfluoroalkyl substances (PFASs) in soil and the carry-over from soil to plants, technical mixtures of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) at a concentration of 25 mg/kg soil were applied to 1.5 m(3) monolithic soil columns of a lysimeter. Growth samples and percolated water were analyzed for PFASs throughout a period of 5 years. In addition to PFOA/PFOS plant compartments and leachate were found to be contaminated with short-chain PFASs. Calculation showed significant decreasing trends (p < 0.05) for all substances tested in the growth samples. Short-chain PFASs and PFOA pass through the soil much more quickly than PFOS. Of the 360 g of PFOA and 367.5 g of PFOS applied to the soil, 96.88% PFOA and 99.98% PFOS were still present in the soil plot of the lysimeter after a period of 5 years. Plants accumulated 0.001% PFOA and 0.004% PFOS. Loss from the soil plot through leachate amounted to 3.12% for PFOA and 0.013% for PFOS.



Zitierstile

Harvard-ZitierstilStahl, T., Riebe, R., Falk, S., Failing, K. and Brunn, H. (2013) Long-Term Lysimeter Experiment To Investigate the Leaching of Perfluoroalkyl Substances (PFASs) and the Carry-over from Soil to Plants: Results of a Pilot Study, Journal of Agricultural and Food Chemistry, 61(8), pp. 1784-1793. https://doi.org/10.1021/jf305003h

APA-ZitierstilStahl, T., Riebe, R., Falk, S., Failing, K., & Brunn, H. (2013). Long-Term Lysimeter Experiment To Investigate the Leaching of Perfluoroalkyl Substances (PFASs) and the Carry-over from Soil to Plants: Results of a Pilot Study. Journal of Agricultural and Food Chemistry. 61(8), 1784-1793. https://doi.org/10.1021/jf305003h



Schlagwörter


carry-overHUMAN-MILKPERFLUORINATED COMPOUNDSPERFLUOROCARBOXYLIC ACIDSPERFLUOROOCTANE SULFONATEPFASsPFCASPFOAspiking

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