Journal article

Near infrared emission spectrum of H13CN


Authors listHofmann, Jan Philipp; Eifert, Bianca; Mellau, Georg Ch.

Publication year2010

Pages75-81

JournalJournal of Molecular Spectroscopy

Volume number262

Issue number2

ISSN0022-2852

DOI Linkhttps://doi.org/10.1016/j.jms.2010.05.005

PublisherElsevier


Abstract
The emission spectrum of (HCN)-C-13 at 1370 K has been recorded with a hot gas high resolution FT-IR emission apparatus [1] in the wavenumber region of 6000-6800 cm(-1) with a resolution of 0.044 cm(-1). This work reports the analysis of 50 subbands for the (HCN)-C-13 isotopologue of hydrogen cyanide in the 2v(1) wavenumber region. 23 rovibronic states of (HCN)-C-13 including the v(1)v(2)'v(3) = 26(6)0 rovibronic states at 10580 cm(-1) have been characterized for the first time and for seven other states it was possible to improve the existing spectroscopic constants substantially. The dense emission spectrum was analyzed with the spectrum analysis software SyMath (TM) implemented in the Mathematica (TM) computer algebra system [1]. (C) 2010 Elsevier Inc. All rights reserved.



Authors/Editors




Citation Styles

Harvard Citation styleHofmann, J., Eifert, B. and Mellau, G. (2010) Near infrared emission spectrum of H13CN, Journal of Molecular Spectroscopy, 262(2), pp. 75-81. https://doi.org/10.1016/j.jms.2010.05.005

APA Citation styleHofmann, J., Eifert, B., & Mellau, G. (2010). Near infrared emission spectrum of H13CN. Journal of Molecular Spectroscopy. 262(2), 75-81. https://doi.org/10.1016/j.jms.2010.05.005



Keywords


Bending vibrationsCoriolis perturbationsDIPOLEEmission spectraFLOPPY MOLECULESH13CNHCNHNCHydrogen cyanideMolecular spectraNear infrared spectraRovibrational constants


SDG Areas


Last updated on 2025-01-09 at 13:11