Journal article

Gas chromatographic determination of amino acid enantiomers in bottled and aged wines


Authors listAli, Hatem Salama Mohammed; Paetzold, Ralf; Brueckner, Hans

Publication year2010

Pages951-958

JournalAmino Acids

Volume number38

Issue number3

ISSN0939-4451

eISSN1438-2199

DOI Linkhttps://doi.org/10.1007/s00726-009-0304-1

PublisherSpringer


Abstract
Free l- and d-amino acids were determined by chiral GC-MS in 26 wines, comprising white wines, red wines, ice wines and sparkling wines. The aim of the work was to investigate whether quantities and pattern of d-amino acids, in particular d-proline, correlate with the storage time of bottled wines. The relative quantities with respect to the corresponding l-enantiomer ranged in white wines from 0.4 to 3.9% d-Ala, 0.9-8.3% d-Asx, and 0.5-8.9% d-Glx, in red wines from 2.9 to 10.6% d-Ala, 2.2-10.9% d-Asx, and 3.9-7.4% d-Glx, and in sparkling wines from 2.2 to 9.8% d-Ala, 2.1-4.4% d-Asx and 1.3-6.1% d-Glx. Low relative quantities of 0.3-0.7% d-Pro were detected in three white wines stored for more than 20 years and did not exceed 0.2% d-Pro in two red wines stored for 10 and 20 years, respectively. An ice wine stored for 24 years contained 0.9% d-Pro, 6.4% d-Glx, 3.0% d-Asp and 1.5% d-Ala. The data confirm the presence of d-amino acids in wines. They do not provide evidence for a correlation between the storage time of bottled wines and quantities of d-amino acids.



Citation Styles

Harvard Citation styleAli, H., Paetzold, R. and Brueckner, H. (2010) Gas chromatographic determination of amino acid enantiomers in bottled and aged wines, Amino Acids, 38(3), pp. 951-958. https://doi.org/10.1007/s00726-009-0304-1

APA Citation styleAli, H., Paetzold, R., & Brueckner, H. (2010). Gas chromatographic determination of amino acid enantiomers in bottled and aged wines. Amino Acids. 38(3), 951-958. https://doi.org/10.1007/s00726-009-0304-1



Keywords


Age datingChirasil (R)-L-ValD-Amino acidsD-ProENOLIZATIONFRUCTOSEMELANOIDINSRACEMIZATION REACTIONSWine amino acids

Last updated on 2025-02-04 at 03:06