Journalartikel

Virgin volcanic rocks: Kinetics and equilibrium studies for the adsorption of cadmium from water


AutorenlisteAlemayehu, Esayas; Lennartz, Bernd

Jahr der Veröffentlichung2009

Seiten395-401

ZeitschriftJournal of Hazardous Materials

Bandnummer169

Heftnummer1-3

ISSN0304-3894

eISSN1873-3336

DOI Linkhttps://doi.org/10.1016/j.jhazmat.2009.03.109

VerlagElsevier


Abstract
This study was initiated to investigate the adsorption of cadmium from aqueous solution by two different rock types-Pumice (VPum) and Scoria (VSco), which are readily available in Ethiopia and other countries. The influence of operational conditions, such as particle size, adsorbent/solution ratio, contact time, cadmium initial concentration, and pH was analyzed. The competition between metals was also evaluated. The Cd(II) removal capacity was predominantly affected by the pH conditions, being increased under alkaline conditions. For both adsorbents, when particle size was 0.075-0.425 mm, the maximum Cd(H) adsorption was observed at pH 6.0 (contact time = 24 h, shaking speed = 200 rpm, adsorbent dose = 50 g L-1). Adsorption process revealed that the initial uptake was very fast during the first 1 h. The kinetics of the interactions follows pseudo second-order. Equilibrium assays confirm that VPum has a larger capacity and affinity for Cd(II) adsorption than VSco. Both Langmuir and Freundlich models described equally well the experimental data. VPum and VSco were found to be promising material for the removal of cadmium from metal bearing water. (C) 2009 Elsevier B.V. All rights reserved.



Zitierstile

Harvard-ZitierstilAlemayehu, E. and Lennartz, B. (2009) Virgin volcanic rocks: Kinetics and equilibrium studies for the adsorption of cadmium from water, Journal of Hazardous Materials, 169(1-3), pp. 395-401. https://doi.org/10.1016/j.jhazmat.2009.03.109

APA-ZitierstilAlemayehu, E., & Lennartz, B. (2009). Virgin volcanic rocks: Kinetics and equilibrium studies for the adsorption of cadmium from water. Journal of Hazardous Materials. 169(1-3), 395-401. https://doi.org/10.1016/j.jhazmat.2009.03.109



Schlagwörter


AQUEOUS-SOLUTIONSpumicescoria

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