Journal article
Authors list: Ipaktschi, Junes; Munz, Frank
Publication year: 2006
Pages: 2078-2082
Journal: European Journal of Inorganic Chemistry
Issue number: 10
ISSN: 1434-1948
eISSN: 1099-0682
DOI Link: https://doi.org/10.1002/ejic.200600056
Publisher: Wiley-VCH Verlag
Abstract:
The reaction of a tungsten acetylide complex [(eta(5)-C5H5)(CO)-(NO)W-C C-R]Li (1) [1a, R = C6H5; 1b, R = C(CH3)3; 1c, R = Si(CH3)31 with one equivalent of ferrocenium, tetrafluoroborate [Cp2Fe][BF4], acting as a one-electron oxidant in THF at -50 degrees C, leads to the bimetallic tungsten-alkynyl complexes [(eta(5)-C5H5)(NO)W-C C-R](2) (9) [9a, R = C6H5; 9b, R = C(CH3) (3); 9c, R = Si(CH3)(3)] as pale-orange crystals. The crystal structure of complex 9a is reported. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim., Germany, 2006.
Citation Styles
Harvard Citation style: Ipaktschi, J. and Munz, F. (2006) Single-electron oxidation of tungsten acetylide complexes [(η5-C5H5)(CO)(NO)W-CC-R]Li, European Journal of Inorganic Chemistry(10), pp. 2078-2082. https://doi.org/10.1002/ejic.200600056
APA Citation style: Ipaktschi, J., & Munz, F. (2006). Single-electron oxidation of tungsten acetylide complexes [(η5-C5H5)(CO)(NO)W-CC-R]Li. European Journal of Inorganic Chemistry(10), 2078-2082. https://doi.org/10.1002/ejic.200600056
Keywords
alkyne ligands; ALKYNYL; BINUCLEAR; Bridging ligands; ETA(2)-ALKYNYL; metal-metal interactions; TRANSITION-METAL-COMPLEXES; VINYLIDENE
