Journal article

Publication year: 2005

Pages: 795-803

Journal: Chemistry of Materials

Volume number: 17

Issue number: 4

ISSN: 0897-4756

eISSN: 1520-5002

DOI Link: https://doi.org/10.1021/cm048287c

Publisher: American Chemical Society

Abstract: 
Arrays of highly ordered Cd1-xMnxS nanciparticles with x ranging from 0.01 to 0.2 and with lateral dimensions of 3, 6, and 9 run were synthesized within mesoporous SiO2 host structures of the MCM-41 and SBA-15 type. The hexagonal symmetry of these arrays (space group p6m) and the high degree of order were confirmed by X-ray diffraction and transmission electron microscope studies. Physisorption measurements show the progressive filling of the pores of the SiO2 host structures, while photoluminescence excitation (PLE) and electron paramagnetic resonance (EPR) studies confirm the good crystalline quality of the incorporated Cd1-xMnxS guest species. The effects of the reduction of the lateral dimensions on the electronic properties of the diluted magnetic semiconductor were studied by PLE spectroscopy. Due to the quantum confinement of the excitons in the nanostructures an increase of the direct band gap with decreasing particle size as well as a stronger band gap bowing is observed. Analysis of the EPR line width and EPR intensity show that macroscopic magnetic properties such as the Curie-Weiss temperature are affected by the reduction of the lateral dimensions. The microscopic coupling between the Mn ions (e.g.. the exchange constants J(nn) and J(nnn)) is not altered to a first approximation.

Harvard Citation style: Brieler, F., Grundmann, P., Fröba, M., Chen, L., Klar, P., Heimbrodt, W., et al. (2005) Size dependence of the magnetic and optical properties of Cd_1-xMn_xS nanostructures confined in mesoporous silica, Chemistry of Materials, 17(4), pp. 795-803. https://doi.org/10.1021/cm048287c

APA Citation style: Brieler, F., Grundmann, P., Fröba, M., Chen, L., Klar, P., Heimbrodt, W., von Nidda, H., Kurz, T., & Loidl, A. (2005). Size dependence of the magnetic and optical properties of Cd_1-xMn_xS nanostructures confined in mesoporous silica. Chemistry of Materials. 17(4), 795-803. https://doi.org/10.1021/cm048287c