Journalartikel

Photoexcitation of a Volume Plasmon in C60 Ions


AutorenlisteScully, SWJ; Emmons, ED; Gharaibeh, MF; Phaneuf, RA; Kilcoyne, ALD; Schlachter, AS; Schippers, S; Müller, A; Chakraborty, HS; Madjet, ME; Rost, JM

Jahr der Veröffentlichung2005

ZeitschriftPhysical Review Letters

Bandnummer94

Heftnummer6

ISSN0031-9007

eISSN1079-7114

DOI Linkhttps://doi.org/10.1103/PhysRevLett.94.065503

VerlagAmerican Physical Society


Abstract
Neutral C-60 is well known to exhibit a giant resonance in its photon absorption spectrum near 20 eV. This is associated with a surface plasmon, where delocalized electrons oscillate as a whole relative to the ionic cage. Absolute photoionization cross-section measurements for C-60(+), C-60(2+), and C-60(3+) ions in the 17-75 eV energy range show an additional resonance near 40 eV. Time-dependent density functional calculations confirm the collective nature of this feature, which is characterized as a dipole-excited volume plasmon made possible by the special fullerene geometry.



Zitierstile

Harvard-ZitierstilScully, S., Emmons, E., Gharaibeh, M., Phaneuf, R., Kilcoyne, A., Schlachter, A., et al. (2005) Photoexcitation of a Volume Plasmon in C60 Ions, Physical Review Letters, 94(6), Article 065503. https://doi.org/10.1103/PhysRevLett.94.065503

APA-ZitierstilScully, S., Emmons, E., Gharaibeh, M., Phaneuf, R., Kilcoyne, A., Schlachter, A., Schippers, S., Müller, A., Chakraborty, H., Madjet, M., & Rost, J. (2005). Photoexcitation of a Volume Plasmon in C60 Ions. Physical Review Letters. 94(6), Article 065503. https://doi.org/10.1103/PhysRevLett.94.065503



Schlagwörter


BUCKMINSTERFULLERENEC60ELECTRON-IMPACTFULLERENE IONSGAS-PHASEPHOTOABSORPTIONPHOTOIONIZATIONSIMPLE METAL-CLUSTERSULTRAVIOLET


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