Journal article

Publication year: 2002

Pages: 189-197

Journal: Journal of Molecular Spectroscopy

Volume number: 211

Issue number: 2

ISSN: 0022-2852

eISSN: 1096-083X

DOI Link: https://doi.org/10.1006/jmsp.2001.8472

Publisher: Elsevier

Abstract: 
High-resolution measurements have been made on the infrared emission spectrum of the doubly substituted HCN isotopomer, (HCN)-C-13-N-15, at temperatures on the order of 1370 K. The measurements cover the region 400-850 cm(-1) with a resolution (1 /MOPD) of 0.006 cm(-1). We could assign hot bands with upper levels up to the 0 11(11) 0 state. The assignments have been verified for states up to v(2) = 5 by fitting with earlier room temperature absorption measurements of overtone and hot bands. All the measurements for (HCN)-C-13-N-15 have been combined in a single least-squares fit that includes approximately 8670 rovibrational lines which have a root-mean-square deviation on the order of 0.000 33 cm(-1). The spectroscopic constants for the bending states v(2) = 1 ..... 11 are reported, as well as those for some combination states involving the two stretching modes. (C) 2002 Elsevier science (USA).

Harvard Citation style: Quapp, W., Melnikov, V. and Mellau, G. (2002) The bending vibrational ladder of H13C15N by hot gas emission spectroscopy, Journal of Molecular Spectroscopy, 211(2), pp. 189-197. https://doi.org/10.1006/jmsp.2001.8472

APA Citation style: Quapp, W., Melnikov, V., & Mellau, G. (2002). The bending vibrational ladder of H13C15N by hot gas emission spectroscopy. Journal of Molecular Spectroscopy. 211(2), 189-197. https://doi.org/10.1006/jmsp.2001.8472