Conference paper

Green emitting molybdate complexes in PbWO4 -: results of an ODMR study


Authors listAlves, H; Hofstaetter, A; Leiter, F; Meyer, BK; Romanov, NG; Novotny, R; Korzhik, MV

Publication year2001

Pages641-644

JournalRadiation Measurements

Volume number33

Issue number5

ISSN1350-4487

DOI Linkhttps://doi.org/10.1016/S1350-4487(01)00075-0

Conference4th European Conference on Luminescent Detectors and Transformers of Ionizing Radiation (LUMDETR 2000)

PublisherElsevier


Abstract
The nature of the green emission of PbWO4 is still under discussion, models ranging from WO3 groups over lead deficient phases to local distortions towards a wolframite structure. In CaWO4 and PbMoO4 optically detected magnetic resonance proved, using resolved Mo hyperfine structure, that tetrahedral MoO4 complexes give rise to a green luminescence. Based on this, we have performed such experiments on a series of PWO samples from various sources and with different dopants. In all cases, we find resonances typical for MoO4 groups, however, with strongly varying intensity depending on the Mo content of the crystals. These ODMR signals are connected with a luminescence band with a half width of 0.43 eV peaking at 508 nm. (C) 2001 Elsevier Science Ltd. All rights reserved.



Citation Styles

Harvard Citation styleAlves, H., Hofstaetter, A., Leiter, F., Meyer, B., Romanov, N., Novotny, R., et al. (2001) Green emitting molybdate complexes in PbWO4 -: results of an ODMR study, Radiation Measurements, 33(5), pp. 641-644. https://doi.org/10.1016/S1350-4487(01)00075-0

APA Citation styleAlves, H., Hofstaetter, A., Leiter, F., Meyer, B., Romanov, N., Novotny, R., & Korzhik, M. (2001). Green emitting molybdate complexes in PbWO4 -: results of an ODMR study. Radiation Measurements. 33(5), 641-644. https://doi.org/10.1016/S1350-4487(01)00075-0



Keywords


green luminescenceLead tungstateODMR

Last updated on 2025-01-04 at 22:32