Conference paper

Photoexcitations in halogen-doped and undoped xenon matrices


Authors listMaier, G; Lautz, C; Reisenauer, HP

Publication year2000

Pages25-38

Volume number25

Issue number1-2

ISSN1025-6008

Conference16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh)


Abstract
Upon photolysis in a bromine-doped xenon matrix with lambda = 254 nm propane (3) can be fragmented despite the fact that 3 does not absorb light of this wavelength. A mechanistic model is developed, which can explain this type of indirect photoexcitation. In addition, the behavior of propane (3) in a pure xenon matrix on irradiation with a laser and a mercury lamp is repel-red. The saturated hydrocarbon 3 is not photostable under these experimental conditions, and the corresponding mechanisms leading to its fragmentation are discussed.



Citation Styles

Harvard Citation styleMaier, G., Lautz, C. and Reisenauer, H. (2000) Photoexcitations in halogen-doped and undoped xenon matrices, 16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh), MUNICH, GERMANY. pp. 25-38

APA Citation styleMaier, G., Lautz, C., & Reisenauer, H. (2000). Photoexcitations in halogen-doped and undoped xenon matrices. 16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh), MUNICH, GERMANY.



Keywords


EXCITONShalogensIR SPECTROSCOPYMETHYLENECYCLOPROPANEPHOTODYNAMICSSOLID XENONTRIMETHYLENEMETHANEtwo-photon processXEXENON

Last updated on 2025-01-04 at 21:10