Journalartikel

Jahr der Veröffentlichung: 1998

Seiten: 1419-1428

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 624

Heftnummer: 9

ISSN: 0044-2313

Verlag: Wiley

Abstract: 
Bonding, structure, and stability of solid A(2)MH(2) with A = Li, Na; M = Pd, Pt were investigated with a relativistically corrected density-functional approach, which reliably describes the trends among these four compounds. In order to examine the influence of the ligands (A) and of the crystalline environment, calculations were also made for free A(2)MH(2) molecules and MH22- ions. The free MH22- complex is held together by strong bonds between formally closed shell atomic units because of strong M-d,s hybridization. The M-H bonds are further stabilized by the alkali metal ion ligands and by the crystal surrounding. The crystal field expands the H-A distance and enhances the H-A polarity. Relativistic effects contribute to M-H bonding in the solid state. The experimentally determined bond lengths and their trends are in accordance with theory. Due to relativistic and lanthanide effects, the Pt-H bond length becomes nearly as short as the Pd-H one. The small Li ion causes a distortion of the Li2PtH2 crystal resulting in an even shorter Pt-H bond length. In the gas-phase, A(2)PtH(2) is more stable against dissociation than A(2)PdH(2). The stability of the solid compounds is strongly influenced by the cohesive energy of the metal M, and also by the nature of the alkali metal. The evaluated enthalpies of formation favor increasing stability of solid A(2)MH(2) against disproportionation into M and AH from Pt to Pd and from Li to Na. This is in agreement with experimental findings. The assignment of the experimental vibrational excitations should be reconsidered.