Journal article

Publication year: 1997

Pages: 5857-5861

Journal: Journal of the American Chemical Society

Volume number: 119

Issue number: 25

ISSN: 0002-7863

DOI Link: https://doi.org/10.1021/ja970300p

Publisher: American Chemical Society

Abstract: 
triplet-4-Methylene-2-pentene-1,5-diyl (T-4t) has been generated upon irradiation of 2-vinylmethylenecyclopropane (6) in a bromine-doped xenon matrix and characterized by means of IR spectroscopy for the first time. Conclusions for the thermal isomerization of 6 to 3-methylenecyclopentene (7) are discussed. All experimental results indicate that this isomerization probably proceeds via the diradical S-4 as an intermediate.

Harvard Citation style: Maier, G. and Senger, S. (1997) 2-vinylmethylenecyclopropane/3-methylene rearrangement: Matrix-infrared spectroscopic identification of 4-methylene-2-pentene-1,5-diyl(1,2'-bisallyl diradical), Journal of the American Chemical Society, 119(25), pp. 5857-5861. https://doi.org/10.1021/ja970300p

APA Citation style: Maier, G., & Senger, S. (1997). 2-vinylmethylenecyclopropane/3-methylene rearrangement: Matrix-infrared spectroscopic identification of 4-methylene-2-pentene-1,5-diyl(1,2'-bisallyl diradical). Journal of the American Chemical Society. 119(25), 5857-5861. https://doi.org/10.1021/ja970300p