Journal article

Publication year: 1996

Pages: 1920-1926

Journal: Journal of Inorganic and General Chemistry

Volume number: 622

Issue number: 11

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19966221118

Publisher: Wiley

Abstract: 

Single crystals of caesium iron hydrogen phosphate, Cs3Fe3H15(PO4)(9), 2, were prepared hydrothermally by heating caesium iron dihydrogenphosphate, CsFe(H2PO4)(4), 1, with a small amount of water. 2 crystallizes orthorhombic, space group Pna2(1) (No. 33 Int. Tab.) with Z = 4 and a = 2718(1), b = 908.1(3), c = 1280.8(4)pm

The crystal structure was solved by using 4734 unique reflections I > 2 sigma(I) with a final wR2 value of 0.0801 (SHELXL-93). The main feature of the crystal structure are channels formed by combined PO4-tetrahedra and FeO6-octahedra along the [001] direction. Cs+ is placed inside of the channels. Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), Charge Distribution (CHARDI) and the Madelung Part of Lattice Energy (MAPLE) are calculated for the title compound.

Harvard Citation style: Anisimova, N., Schulke, U., Bork, M., Hoppe, R. and Serafin, M. (1996) Preparation and crystal structure of a new acentric caesium iron hydrogenphosphate, Cs3Fe3H15(PO4)(9), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 622(11), pp. 1920-1926. https://doi.org/10.1002/zaac.19966221118

APA Citation style: Anisimova, N., Schulke, U., Bork, M., Hoppe, R., & Serafin, M. (1996). Preparation and crystal structure of a new acentric caesium iron hydrogenphosphate, Cs3Fe3H15(PO4)(9). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 622(11), 1920-1926. https://doi.org/10.1002/zaac.19966221118