Journal article

Publication year: 1996

Pages: 1715-1720

Journal: Journal of Inorganic and General Chemistry

Volume number: 622

Issue number: 10

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19966221015

Publisher: Wiley

Abstract: 

Colourless, square stonelike single crystals of CsNa3[TiO4] [1], isostructural with CsNa3[PbO4] [2], are obtained by heating a well grounded mixture of the binary oxides Cs-0,Cs-56, NaO0,52 and TiO2 (Cs:Na:Ti = 1,1:3,1:1,0) in Nitubes (9d, 400 degrees C).

The structure determination by using four-circle diffactometer data (Siemens AED2, 5541 I-o(hkl), ) leads to the residual-values R = 8.8% and R(w) = 4.7%. Lattice constants (triclinic, Cmca, , Z = 4, four-circle diffactometer data, : a = 1161.2(6) pm, b = 854.9(3) pm, c = 651.1(3) pm, alpha = 100.52(2)degrees, beta = 108.84(3)degrees, gamma = 91.61(3)degrees; additional data see text).

The Madelung Part of Lattice Energy (MAPLE), Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR) and the Charge Distribution in Solids (CHARDI) are calculated and discussed.

Harvard Citation style: Weiss, C. and Hoppe, R. (1996) The new orthotitanate CsNa3[TiO4], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 622(10), pp. 1715-1720. https://doi.org/10.1002/zaac.19966221015

APA Citation style: Weiss, C., & Hoppe, R. (1996). The new orthotitanate CsNa3[TiO4]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 622(10), 1715-1720. https://doi.org/10.1002/zaac.19966221015