Journal article

Publication year: 1996

Pages: 1721-1728

Journal: Journal of Inorganic and General Chemistry

Volume number: 622

Issue number: 10

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19966221016

Publisher: Wiley

Abstract: 
Green single crystals were obtained by heating (Au-tube, 450 degrees-500 degrees C) a mixture of SnF2 and AuF3 (Sn:Au = 1:1) which correspond to the SnF4-type [2, 3] (two single crystals, A: 762 I-o, R1 = 2.4%; B: 1591 I-o, R1 = 1.2% (SHELXL-93); I4/mmm (No. 139); B: a = 404.8(1) pm, c = 796.4(1) pm, c/a = 1.97, Z(F2) = 0.2354). Due to atom absorption and Mossbauer measurements the crystals contain Au. The compound is paramagnetic and follows the Curie-Wei ss law (14.7-251.3 K, theta = -12 K, mu/mu(B) = 1.55). ESR-experiments confirm that Au is surrounded by 6 F- according to Sn in SnF4 (2 short (187.5 pm) and 4 longer (202.4 pm) distances). The observed Mossbauer spectra could not be interpreted yet, but they don't correspond to any known.

Harvard Citation style: Bork, M., Hoppe, R., Hofstaetter, A., Scharmann, A. and Wagner, F. (1996) A green paramagnetic gold fluoride - Sn1-xAuxF4?, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 622(10), pp. 1721-1728. https://doi.org/10.1002/zaac.19966221016

APA Citation style: Bork, M., Hoppe, R., Hofstaetter, A., Scharmann, A., & Wagner, F. (1996). A green paramagnetic gold fluoride - Sn1-xAuxF4?. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 622(10), 1721-1728. https://doi.org/10.1002/zaac.19966221016