Journal article

Microscopic explanation of the non-arrhenius conductivity in glassy fast ionic conductors


Authors listMaass, P; Meyer, M; Bunde, A; Dieterich, W

Publication year1996

Pages1528-1531

JournalPhysical Review Letters

Volume number77

Issue number8

ISSN0031-9007

DOI Linkhttps://doi.org/10.1103/PhysRevLett.77.1528

PublisherAmerican Physical Society


Abstract
To explore the origin of the recently discovered non-Arrhenius behavior of the de conductivity in glassy fast ionic conductors at high temperatures, we investigate by Monte Carlo simulations the transport of charged particles in an energetically disordered structure. We show that the combined effect of Coulomb interaction and disorder can account for the experimental findings. Our results suggest that glassy superionic conductors can be optimized by lowering the strength of the energetic disorder but that the ionic interaction effects set an upper bound for the conductivity at high temperatures.



Citation Styles

Harvard Citation styleMaass, P., Meyer, M., Bunde, A. and Dieterich, W. (1996) Microscopic explanation of the non-arrhenius conductivity in glassy fast ionic conductors, Physical Review Letters, 77(8), pp. 1528-1531. https://doi.org/10.1103/PhysRevLett.77.1528

APA Citation styleMaass, P., Meyer, M., Bunde, A., & Dieterich, W. (1996). Microscopic explanation of the non-arrhenius conductivity in glassy fast ionic conductors. Physical Review Letters. 77(8), 1528-1531. https://doi.org/10.1103/PhysRevLett.77.1528



Keywords


DISORDERED-SYSTEMS

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