Journalartikel
Autorenliste: Maier, G; Senger, S
Jahr der Veröffentlichung: 1996
Seiten: 45-47
Zeitschrift: Liebigs Annalen - recueil
Heftnummer: 1
ISSN: 0947-3440
Verlag: Wiley-VCH Verlag
Abstract:
Irradiation (lambda = 254 nm) of cyclobutane in a bromine-doped xenon matrix leads to ring opening in spite of the fact that cyclobutane does not absorb in this region. The main products are ethene and 1-butene. The same reaction, but less effectively, occurs upon irradiation with a laser (KrF laser, lambda = 248 nm) in the absence of the halogen. The difference in the mechanisms of the two fragmentations is discussed.
Zitierstile
Harvard-Zitierstil: Maier, G. and Senger, S. (1996) Small rings .91. Fragmentation of cyclobutane in a bromine-doped and undoped xenon matrix, Liebigs Annalen - recueil(1), pp. 45-47
APA-Zitierstil: Maier, G., & Senger, S. (1996). Small rings .91. Fragmentation of cyclobutane in a bromine-doped and undoped xenon matrix. Liebigs Annalen - recueil(1), 45-47.
Schlagwörter
CHARGE-TRANSFER STATES; exciplexes; EXCITONS; matrix spectroscopy; PHOTODYNAMICS; PHOTOLYSIS; ring opening; SOLID XENON; XE
