Journal article

Publication year: 1995

Pages: 6202-620&

Journal: Inorganic Chemistry

Volume number: 34

Issue number: 24

ISSN: 0020-1669

DOI Link: https://doi.org/10.1021/ic00128a036

Publisher: American Chemical Society

Abstract: 
From WCl6 and selenium Se-17(2+)(WCl6-)(2) is formed in a solid state reaction at 110 degrees C. The structure of the dark red crystals consists of Se-17(2+) polycations built of two seven membered Se rings in the chair confer mation connected by a Se-3 chain, and of distorted octahedral WCl6- anions. The two positive charges of each ion are formally localized on the two triply bound Se atoms. The structure of Se-17(2+) is closely related to that of the previously known S-19(2+).

Harvard Citation style: BECK, J. and WETTERAU, J. (1995) CHALCOGEN POLYCATIONS BY OXIDATION OF ELEMENTAL CHALCOGENS WITH TRANSITION-METAL HALIDES - SYNTHESIS AND CRYSTAL-STRUCTURE OF [SE-17][WCL6](2), Inorganic Chemistry, 34(24), pp. 6202-620&. https://doi.org/10.1021/ic00128a036

APA Citation style: BECK, J., & WETTERAU, J. (1995). CHALCOGEN POLYCATIONS BY OXIDATION OF ELEMENTAL CHALCOGENS WITH TRANSITION-METAL HALIDES - SYNTHESIS AND CRYSTAL-STRUCTURE OF [SE-17][WCL6](2). Inorganic Chemistry. 34(24), 6202-620&. https://doi.org/10.1021/ic00128a036