Journal article

Publication year: 1995

Pages: 1069-1074

Journal: Journal of Inorganic and General Chemistry

Volume number: 621

Issue number: 6

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19956210630

Publisher: Wiley

Abstract: 

Cesium gallium hydrogen triphosphate CsGaHP3O10-III crystallizes in the space group Pca2(1), a = 1176.3(1)pm, b = 496.55(5) pm, c = 1572.2(1) pm and Z = 4.

The structure was solved by using 1268 unique reflections I-o > 2 sigma(I-o) with a final wR2 value of 0.0742 (SHELXL-93).

The P3O10 chain anions, bonded by Ga, are spreaded in layers parallel (001); the layers are interconnected by Cs-polyhedra and obviously by hydrogen bonds. The interlayer distance is c/2.

The new structure is compared with the previously known structures of CsGaHP3O10-I and CS3Ga3P12O(36).

Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), and the Charge Distribution (CHARDI) are calculated for the title compound.

Harvard Citation style: ANISIMOVA, N., BORK, M., HOPPE, R. and MEISEL, M. (1995) CRYSTAL-STRUCTURE OF A NEW ACENTRIC CSGAHP3O10 FORM III, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 621(6), pp. 1069-1074. https://doi.org/10.1002/zaac.19956210630

APA Citation style: ANISIMOVA, N., BORK, M., HOPPE, R., & MEISEL, M. (1995). CRYSTAL-STRUCTURE OF A NEW ACENTRIC CSGAHP3O10 FORM III. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 621(6), 1069-1074. https://doi.org/10.1002/zaac.19956210630