Journalartikel

Jahr der Veröffentlichung: 1995

Seiten: 1042-1046

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 621

Heftnummer: 6

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19956210625

Verlag: Wiley

Abstract: 
The reaction of SeBr4 and AlBr3 in a closed glass ampoule at 150 degrees C yields quantitatively SeBr3[AlBr4] in form of yellow moisture sensitive crystals. From Te, two equivalents of I-2 and AlI4 one obtains TeI3[AlI4] in form of dark red, moisture sensitive crystals. Both compounds crystallize monoclinic in the space group Pc (SeBr3[AlBr4]: a = 670.7(7)pm, b = 663.9(5) pm, c = 1428.6(2)pm, beta = 101.21(9)degrees, TeI3[AlI4]: a = 731.9(1) pm, b = 730.8(1) pm, c = 1565.5(3)pm, beta = 102.01(2)degrees). They are isotypic and have the SCl3[AlCl4] structure type. The structures are built of tetrahedral AlX(4) ions and of pyramidal EX(3)(+) ions (E = S, Se, Te; X = Cl, Br, I). The chalcogen atoms are additionally coordinated by halogen atoms of surrounding AlX(4)(-) ions, corresponding to a strongly distorted octahedral coordination EX(3+3).

Harvard-Zitierstil: BECK, J. and FISCHER, A. (1995) SEBR3[ALBR4] AND TEI3[ALI4] - 2 FURTHER COMPOUNDS IN THE SCL3[ALCL4] STRUCTURE TYPE, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 621(6), pp. 1042-1046. https://doi.org/10.1002/zaac.19956210625

APA-Zitierstil: BECK, J., & FISCHER, A. (1995). SEBR3[ALBR4] AND TEI3[ALI4] - 2 FURTHER COMPOUNDS IN THE SCL3[ALCL4] STRUCTURE TYPE. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 621(6), 1042-1046. https://doi.org/10.1002/zaac.19956210625