Journal article

Publication year: 1995

Pages: 713-718

Journal: Journal of Inorganic and General Chemistry

Volume number: 621

Issue number: 5

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19956210503

Publisher: Wiley

Abstract: 
By heating the binary oxides CsO0.52, NaO0.45, LiO0.5 and GeO2 in the mel. ratio 1.24:1.4:6.7:3.9 (Ni tubes; 600 degrees C / 89 resp. 65d) we obtained for the first time CsNa3Li8}Li[GeO4]}(4) in form of pale yellow prisms as well as powder: space group I4/m (I. T. No. 87) with a = 1120.73(5); c = 651.64(5) pm; Z = 2; (four circle diffractometer data; MoK alpha; 5152I(o)(hkl); R = 1.7%; R(w) = 1.6%), parameters see text. The structure determination confirmes its being isotypic with CsKNaLi9{Li[SiO4]}(4), CsKNa2Li8{Li[SiO4]}(4) and RbNa3Li8{Li[SiO4]}(4). The Madelung part of lattice energy (MAPLE), effective coordination numbers (ECoN), mean fictive ionic radii (MEFIR) and the charge distribution (CHARDI) are calculated.

Harvard Citation style: BRANDES, R. and HOPPE, R. (1995) THE 1ST OXOGERMANATE WITH STUFFED PYRGOMS - CSNA3LI8(LI[GEO4])(4), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 621(5), pp. 713-718. https://doi.org/10.1002/zaac.19956210503

APA Citation style: BRANDES, R., & HOPPE, R. (1995). THE 1ST OXOGERMANATE WITH STUFFED PYRGOMS - CSNA3LI8(LI[GEO4])(4). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 621(5), 713-718. https://doi.org/10.1002/zaac.19956210503