Journal article

Publication year: 1995

Pages: 177-180

Journal: Journal of Inorganic and General Chemistry

Volume number: 621

Issue number: 2

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19956210202

Publisher: Wiley

Abstract: 

By heating of well ground mixtures of the oxides RbO0.9 and Li[MnO4] (Rb:Mn = 1.5:1; Ag-tubes; 660-degrees-C, 56 d) dark-green, orthorhombic single-crystals of Rb2[MnO4] were obtained. The structural determination revealed the isotype to K2[MnO4]; a beta-K2SO4-typ. Thus, for the first time by a pure solid-state-chemical way, via a reductive, complete alkali-metal exchange, single crystals of an oxomanganate(VI) of the alkali metals were prepared.

The Madelung Part of the Lattice Energy, MAPLE, and the charge distribution were calculated.

Harvard Citation style: FISCHER, D. and HOPPE, R. (1995) A REDUCTIVE EXCHANGE-REACTION - SINGLE-CRYSTALS OF RB2[MNO4] FROM LI[MNO4], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 621(2), pp. 177-180. https://doi.org/10.1002/zaac.19956210202

APA Citation style: FISCHER, D., & HOPPE, R. (1995). A REDUCTIVE EXCHANGE-REACTION - SINGLE-CRYSTALS OF RB2[MNO4] FROM LI[MNO4]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 621(2), 177-180. https://doi.org/10.1002/zaac.19956210202