Journal article
Authors list: BECK, J
Publication year: 1995
Pages: 131-136
Journal: Journal of Inorganic and General Chemistry
Volume number: 621
Issue number: 1
ISSN: 0044-2313
DOI Link: https://doi.org/10.1002/zaac.19956210124
Publisher: Wiley
Abstract:
Dark green, very air sensitive crystals of Se-4(MoOCl4)(2) are formed from selenium and MoOCl4 at 190 degrees C in a sealed, evacuated glass ampoule;in quantitative yield. The structure is built of nearly square planar Se-4(2+) ions and centrosymmetric dimeric MoOCl4- ions which are linked by bridging Cl atoms. At -21 degrees C Se-4(MoOCl4)(2) undergoes a reversible solid state phase transition of first order. Structure determinations at -70 degrees C and 23 degrees C show that during the phase transition the structures of the ions remain unchanged, while the orientations of the ions with respect to each other change in such a way that in the low temperature form the Se-4(2+) ions obtain a higher coordination number by Cl and O atoms of neighboring MoOCl4- ions.
Citation Styles
Harvard Citation style: BECK, J. (1995) SYNTHESIS, CRYSTAL-STRUCTURE, AND PHASE-TRANSITION OF SE-4(MOOCL4)(2), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 621(1), pp. 131-136. https://doi.org/10.1002/zaac.19956210124
APA Citation style: BECK, J. (1995). SYNTHESIS, CRYSTAL-STRUCTURE, AND PHASE-TRANSITION OF SE-4(MOOCL4)(2). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 621(1), 131-136. https://doi.org/10.1002/zaac.19956210124
Keywords
preparation; TETRASELENIUM(2+) BIS(TETRACHLOROOXOMOLYBDATE)-(2-)
