Journalartikel

Jahr der Veröffentlichung: 1994

Seiten: 2026-2032

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 620

Heftnummer: 12

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946201203

Verlag: Wiley

Abstract: 

Colourless crystals of Li10Si2PbO10 were obtained by heating a well-ground mixture of LiPb, Li2O2 and ,,SiO2'' (deriving from Duran glas) in Ag-tubes (650 degrees C; 60 d). The crystal structure was determined (four-circle diffractometer data, Mo-K ($) over bar alpha, 1474 I-degrees(hkl), R = 4.2%, R(w) = 2.8%, parameters see text). The silicate-plumbate crystallizes monoclinic (space group C2/m; I. T. No. 12) with a = 2985.1(4); b = 610.6(6); c = 512.8(1) pm, beta = 99.70(9)degrees (four-circle data), Z = 4.

Further the Madelung Part of Lattice Energy (MAPLE), Effective Coordination Numbers (ECoN), the Mean Fictive Ionic Radii (MEFIR) and the Charge Distribution (CHARDI) are being calculated.

Harvard-Zitierstil: BRANDES, R. and HOPPE, R. (1994) (LI10SI2PBO10)-O-II=LI-20[(SIO4)(4)(OPBO2PBO)] - THE FIRST MIXED SILICATE-PLUMBATE(II), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(12), pp. 2026-2032. https://doi.org/10.1002/zaac.19946201203

APA-Zitierstil: BRANDES, R., & HOPPE, R. (1994). (LI10SI2PBO10)-O-II=LI-20[(SIO4)(4)(OPBO2PBO)] - THE FIRST MIXED SILICATE-PLUMBATE(II). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(12), 2026-2032. https://doi.org/10.1002/zaac.19946201203