Journal article
Authors list: SCHLAGER, M; HOPPE, R
Publication year: 1994
Pages: 1867-1871
Journal: Journal of Inorganic and General Chemistry
Volume number: 620
Issue number: 11
ISSN: 0044-2313
DOI Link: https://doi.org/10.1002/zaac.19946201106
Publisher: Wiley
Abstract:
Colourless single crystals of CsBO2 have been prepared from intimate mixtures of CsO0.57 and B2O3 (Cs:B = 3.2:1.0; 600 degrees C, 38 d). The structure determination from four-circle diffractometer data (MoK<(alpha)over bar>, 443 I-o (h k l), R = 3.1%, R(w) = 2.0%) confirms the isotypy with NaBO2 and KBO2: space group R (3) over bar c; a = 1363.7(2) pm, c = 836.5(2) pm; Z = 18. A characteristic structure unit is the planar cyclic anion [B3O6](3-).
Effective Coordination Numbers (ECoN), Mean Fictive Ionic Radii (MEFIR), the Madelung Part of Lattice Energy (MAPLE) and the Charge Distribution (CHARDI) are calculated and discussed.
Citation Styles
Harvard Citation style: SCHLAGER, M. and HOPPE, R. (1994) PREPARATION AND CRYSTAL-STRUCTURE OF CSBO2, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(11), pp. 1867-1871. https://doi.org/10.1002/zaac.19946201106
APA Citation style: SCHLAGER, M., & HOPPE, R. (1994). PREPARATION AND CRYSTAL-STRUCTURE OF CSBO2. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(11), 1867-1871. https://doi.org/10.1002/zaac.19946201106
Keywords
CALCULATION OF ECON, MEFIR, MAPLE, CHARDI; CESIUM METABORATE, CSBO2
