Journalartikel

Jahr der Veröffentlichung: 1994

Seiten: 2583-2587

Zeitschrift: Polyhedron

Bandnummer: 13

Heftnummer: 17

ISSN: 0277-5387

DOI Link: https://doi.org/10.1016/S0277-5387(00)83103-4

Verlag: Elsevier

Abstract: 
The reaction between PtCl2(PhCN)2 and N,N-dimethyl phenyl propargyl amine (1) affords trans-[Pt(N(Me2)CH2C=CPh)(NCPh)Cl2] (3) which formally undergoes trans-Cl- addition onto its C=C bond to give [Pt(C(Ph) = C(Cl)CH2NMe2)(NCPh)Cl] (4). On the other hand, the cis-nucleophilic addition product trans-{Pt[cis-(o-NC5H4) CH=C(Ph)(NEt2)]Cl2(HNEt2)} (6) was obtained quantitatively from the reaction of a large excess of diethylamine with trans-[Pt(o-NC5H4)CH=C(Ph)(SEt2)Cl2] (5).

Harvard-Zitierstil: DUPONT, J., CASAGRANDE, O., AIUB, A., BECK, J., HORNER, M. and BORTOLUZZI, A. (1994) CIS AND TRANS NUCLEOPHILIC ADDITIONS ON C=C BONDS ASSISTED BY PT(II) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF TRANS-(PT[CIS-(O-NC5H4)CH=C(PH)(NET2)]CL2(HNET2)), Polyhedron, 13(17), pp. 2583-2587. https://doi.org/10.1016/S0277-5387(00)83103-4

APA-Zitierstil: DUPONT, J., CASAGRANDE, O., AIUB, A., BECK, J., HORNER, M., & BORTOLUZZI, A. (1994). CIS AND TRANS NUCLEOPHILIC ADDITIONS ON C=C BONDS ASSISTED BY PT(II) COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF TRANS-(PT[CIS-(O-NC5H4)CH=C(PH)(NET2)]CL2(HNET2)). Polyhedron. 13(17), 2583-2587. https://doi.org/10.1016/S0277-5387(00)83103-4