Journal article

Publication year: 1994

Pages: 1179-1184

Journal: Journal of Inorganic and General Chemistry

Volume number: 620

Issue number: 7

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946200709

Publisher: Wiley

Abstract: 
For the first time Na26O3[InO4]4 was obtained by annealing intimate mixtures of Na2O, CdO and elemental In (molar ratio 3.5:1.0:2.0) in closed Ni-cylinders (30 days, 600-degrees-C) in form of yellow single crystals. The structure determination by four circle diffractometer data (MoKalpha, 921 out of 921 I(o)(hkl), R = 2.53, R(w) = 2.18%) confirms the space group 143dBAR (cubic) with a = 1 427.37 pm and Z = 4. All kation are surrounded by tetrahedron of O2-. In3+ is coordinated with O(1) and O(2) (without O(3)) only. There are ''isolated'' [InO4]-tetrahedra. The Madelung Part of Lattice Energy, MAPLE, the Mean Fictive Ionic Radii, MEFIR, Effective Coordination Numbers, ECoN, and Charge Distribution, CHARDI, are calculated.

Harvard Citation style: LULEI, M. and HOPPE, R. (1994) THE 1ST BASIC OXOINDATE - NA26O3[INO4]4, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(7), pp. 1179-1184. https://doi.org/10.1002/zaac.19946200709

APA Citation style: LULEI, M., & HOPPE, R. (1994). THE 1ST BASIC OXOINDATE - NA26O3[INO4]4. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(7), 1179-1184. https://doi.org/10.1002/zaac.19946200709