Journal article

Publication year: 1994

Pages: 839-846

Journal: Journal of Inorganic and General Chemistry

Volume number: 620

Issue number: 5

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946200515

Publisher: Wiley

Abstract: 
Transport experiments in the system Cr/Nb/O yielded the compound (Cr, Nb)12O29 as crystalline green needles. The lattice parameters of the monoclinic cell are a = 31.162(8) angstrom, b = 3.8324(6) angstrom, c = 20.579(6) angstrom, beta = 113.22(3)-degrees. (Cr, Nb)12O29 is isotypic with monoclinic Nb12O29 as shown by Guinier diagrams and high resolution transmission electron microscopy. Characteristic structural building elements are [3x4]-blocks which are columnar sections from the ReO3 structure. In the real structure one finds numerous defects. Under the influence of the electron beam we observed reversible changes of contrast which indicates that the positions of the M-particles (M = Cr, Nb) have shifted.

Harvard Citation style: HOFFMANN, G., ROSS, R. and GRUEHN, R. (1994) CONTRIBUTIONS TO THE INVESTIGATION OF INORGANIC NONSTOICHIOMETRIC COMPOUNDS .43. PREPARATION AND ELECTRON-MICROSCOPIC INVESTIGATION OF (CR, NB)12O29, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(5), pp. 839-846. https://doi.org/10.1002/zaac.19946200515

APA Citation style: HOFFMANN, G., ROSS, R., & GRUEHN, R. (1994). CONTRIBUTIONS TO THE INVESTIGATION OF INORGANIC NONSTOICHIOMETRIC COMPOUNDS .43. PREPARATION AND ELECTRON-MICROSCOPIC INVESTIGATION OF (CR, NB)12O29. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(5), 839-846. https://doi.org/10.1002/zaac.19946200515