Journal article

Publication year: 1994

Pages: 777-780

Journal: Journal of Inorganic and General Chemistry

Volume number: 620

Issue number: 5

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946200502

Publisher: Wiley

Abstract: 
For the first time CsK4[TlO4] was obtained by heating intimate mixtures of K2O, CdO and CsTl (molar ratio 3.1: 1.0: 1.0) in closed Ag-cylinders (25 days, 450-degrees-C) in form of yellow, transparent single crystals. The structure determination by four circle diffractometer data (MoKalpha, 1922 out of 2094 I(o)(hkl), R = 2.98, R(w) = 2.49) confirms the space group Pbca with lattice constants a = 1192.1 pm; b = 685.7 pm; c = 2143.5 pm; Z = 8. The structure is isotypic with Na5[GaO4]. The Madelung Part of Lattice Energy, MAPLE, the Mean Fictive Ionic Radii, MEFIR, Effective Coordination Numbers, ECoN, and Charge Distribution, CHARDI, are calculated.

Harvard Citation style: LULEI, M. and HOPPE, R. (1994) THE 1ST OXOTHALLATE(III) WITH THE FORMULA TYPE AA4'[MO4] - CSK4[TLO4], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(5), pp. 777-780. https://doi.org/10.1002/zaac.19946200502

APA Citation style: LULEI, M., & HOPPE, R. (1994). THE 1ST OXOTHALLATE(III) WITH THE FORMULA TYPE AA4'[MO4] - CSK4[TLO4]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(5), 777-780. https://doi.org/10.1002/zaac.19946200502