Journal article

Publication year: 1994

Pages: 586-591

Journal: Journal of Inorganic and General Chemistry

Volume number: 620

Issue number: 4

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946200403

Publisher: Wiley

Abstract: 

By ''reaction with the cylinder surface'' of intimate mixtures of K2O and CdO (molar ratio 1 : 1) in closed Co-Cylinders at 450-degrees-C during 73 d dark-red single-crystals of K2CoO2 were obtained.

Structure solution and refinement (four-circle diffractometer-data, MoKalphaBAR, 1567 independent I(o)(hkl), none was omitted, R = 3.25%, R(w) = 2.67%) result in a monoclinic unit cell containing anions [Co2O4]4- of two connected triangles similar to those of Rb10[CoIO2]2[Co2IIO4]. MAPLE-values and Charge-distributions are given and discussed.

Harvard Citation style: BERNHARDT, F. and HOPPE, R. (1994) THE 1ST OXOCOBALTATE OF THE TYPE A2CO(II)O2K2COO2=K4[OCOO2COO], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(4), pp. 586-591. https://doi.org/10.1002/zaac.19946200403

APA Citation style: BERNHARDT, F., & HOPPE, R. (1994). THE 1ST OXOCOBALTATE OF THE TYPE A2CO(II)O2K2COO2=K4[OCOO2COO]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(4), 586-591. https://doi.org/10.1002/zaac.19946200403