Journal article

Publication year: 1994

Pages: 187-191

Journal: Journal of Inorganic and General Chemistry

Volume number: 620

Issue number: 2

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946200202

Publisher: Wiley

Abstract: 

Dark-red single crystals of CsK2[CoO2] were obtained via ''reaction with the cyliner surface'' by heating powders of Cs2K2Cd3O5 in closed Co-cylinders at 500-degrees-C during 48 d.

Structure solution and refinement (four-circle diffractometer data, MoKalphaBAR, 147 independent I(o)(hkl), none was omitted, R = 3.42%, R(w) = 2.24%) show close relationship with RbNa2[NiO2] [2].

The lattice-constants are: a = 529.506(5) pm, c = 986.18(1) pm, Z = 2 (powder data, standard deviations in parentheses) MAPLE calculations, investigations of magnetism and EPR measurement add to the monovalence of Co.

Harvard Citation style: BERNHARDT, F., HOPPE, R. and KREMER, R. (1994) THE 1ST QUATERNARY OXIDE OF MONOVALENT COBALT - CSK2[COO2] .1., Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(2), pp. 187-191. https://doi.org/10.1002/zaac.19946200202

APA Citation style: BERNHARDT, F., HOPPE, R., & KREMER, R. (1994). THE 1ST QUATERNARY OXIDE OF MONOVALENT COBALT - CSK2[COO2] .1.. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(2), 187-191. https://doi.org/10.1002/zaac.19946200202