Journal article

Publication year: 1993

Pages: 3397-3401

Journal: Inorganic Chemistry

Volume number: 32

Issue number: 16

ISSN: 0020-1669

DOI Link: https://doi.org/10.1021/ic00068a005

Publisher: American Chemical Society

Abstract: 
The electronic spectrum and temperature dependence of the magnetic susceptibility of powdered KAlCuF6 is reported and shown to be consistent with the compressed tetragonal geometry of the CuF64- groups in this compound. Angular overlap bonding parameters are derived and used to estimate the magnetic coupling between the Cu2+ ions, which are linked in chains via the axial fluoride ligands. Good agreement is obtained with the observed exchange coupling constant J = -60 cm-1, and it is shown that this coupling is expected to be strongly dependent on the CuFCu bridging angle.

Harvard Citation style: ATANASOV, M., HITCHMAN, M., HOPPE, R., MURRAY, K., MOUBARAKI, B., REINEN, D., et al. (1993) THE COMPRESSED TETRAGONAL CUF6(4-) COMPLEX IN KALCUF6 - AN ANGULAR OVERLAP TREATMENT OF THE ELECTRONIC-STRUCTURE AND MAGNETIC EXCHANGE COUPLING, Inorganic Chemistry, 32(16), pp. 3397-3401. https://doi.org/10.1021/ic00068a005

APA Citation style: ATANASOV, M., HITCHMAN, M., HOPPE, R., MURRAY, K., MOUBARAKI, B., REINEN, D., & STRATEMEIER, H. (1993). THE COMPRESSED TETRAGONAL CUF6(4-) COMPLEX IN KALCUF6 - AN ANGULAR OVERLAP TREATMENT OF THE ELECTRONIC-STRUCTURE AND MAGNETIC EXCHANGE COUPLING. Inorganic Chemistry. 32(16), 3397-3401. https://doi.org/10.1021/ic00068a005