Journal article

DETECTION OF TRIMETHYLENEMETHANE BY IR SPECTROSCOPY - THE RESULT OF AN UNEXPECTED PHOTOISOMERIZATION OF METHYLENECYCLOPROPANE IN A HALOGEN-DOPED XE MATRIX


Authors list: MAIER, G; REISENAUER, HP; LANZ, K; TROSS, R; JURGEN, D; HESS, BA; SCHAAD, LJ

Publication year: 1993

Pages: 74-76

Journal: Angewandte Chemie International Edition in English

Volume number: 32

Issue number: 1

ISSN: 0570-0833

DOI Link: https://doi.org/10.1002/anie.199300741

Publisher: Wiley-VCH


Abstract: 
When photolysis and pyrolysis fail, how can(~)the ring-opening of methylenepropene (1) be induced to give trimethylenemethane (2), the first member of the series of non-Kekule hydrocarbons? Can enough 2 be generated for the spectroscopic study of this highly reactive species? These questions are answered in this communication. [GRAPHICS]



Citation Styles

Harvard Citation style: MAIER, G., REISENAUER, H., LANZ, K., TROSS, R., JURGEN, D., HESS, B., et al. (1993) DETECTION OF TRIMETHYLENEMETHANE BY IR SPECTROSCOPY - THE RESULT OF AN UNEXPECTED PHOTOISOMERIZATION OF METHYLENECYCLOPROPANE IN A HALOGEN-DOPED XE MATRIX, Angewandte Chemie International Edition in English, 32(1), pp. 74-76. https://doi.org/10.1002/anie.199300741

APA Citation style: MAIER, G., REISENAUER, H., LANZ, K., TROSS, R., JURGEN, D., HESS, B., & SCHAAD, L. (1993). DETECTION OF TRIMETHYLENEMETHANE BY IR SPECTROSCOPY - THE RESULT OF AN UNEXPECTED PHOTOISOMERIZATION OF METHYLENECYCLOPROPANE IN A HALOGEN-DOPED XE MATRIX. Angewandte Chemie International Edition in English. 32(1), 74-76. https://doi.org/10.1002/anie.199300741



Keywords

ACTIVATION-ENERGY; DIRADICALS; ORGANIC-MOLECULES; PHOTODYNAMICS; RING-CLOSURE; SOLID MATRIX; WAVE-FUNCTIONS; XENON

Last updated on 2025-02-04 at 06:46