Journalartikel

Jahr der Veröffentlichung: 1993

Seiten: 193-201

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 619

Heftnummer: 1

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19936190132

Verlag: Wiley

Abstract: 

By ''reaction with the wall'' of the Fe-cylinders used here we synthesized the new oxoferrates(II) CS6[Fe2O5], CS3.5Rb2.5[Fe2O5] and Rb4K2[Fe2O5] in the form of red single crystals. The structure elucidation via four-circle-diffractometer data shows that the new oxoferrates(II) are isotypic with CS2(Cs0.35K1.65)K2[Fe2O5]. In the structure we have isolated binuclear groups [(O1)2Fe-O(2)-Fe(O1)2]6-. Structure refinements is possible in the centrosymmetrial space group C2/m as well as in the space groups C2 and Cm without centre of symmetry.

The existence of two further oxoferrates(II) CS6-xRbx[Fe2O5] and Cs6-xKx[Fe2O5] which can be described as solid solutions was confirmed by power-data.

Harvard-Zitierstil: MULLER, H. and HOPPE, R. (1993) NEWS ABOUT BINUCLEAR OXOFERRATES(II) [1], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 619(1), pp. 193-201. https://doi.org/10.1002/zaac.19936190132

APA-Zitierstil: MULLER, H., & HOPPE, R. (1993). NEWS ABOUT BINUCLEAR OXOFERRATES(II) [1]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 619(1), 193-201. https://doi.org/10.1002/zaac.19936190132