Journal article

Publication year: 1992

Pages: 59-62

Journal: Journal of Inorganic and General Chemistry

Volume number: 618

Issue number: 12

ISSN: 0044-2313

Publisher: Wiley

Abstract: 

By heating intimate mixtures of the oxides [CsO1.2, Li2MnO3; Cs : Mn = 2.3 : 1; Ag-Zylinder, 580-degrees-C, 62 d] blue-green single crystals of Cs2{Li[MnO4]} were obtained for the first time. The new ''Litho-Manganate(V)'' crystallices orthorhombic (SG: Cmc2(1)) with a = 596.08(7), b = 1202.6(1), c = 816.8(1) pm (Guinier-Simon data), Z = 4. It is isotypic with Cs2{Li[VO4]} [1].

The structure was determined by four-circle-diffractometer data [Mo-KalphaBAR, for 496 I(o)(hkl) R = 3.1 %, R(w) = 2.4%], parameters see text.

The Madelung Part of Lattice Energie, MAPLE and Effective Coordination Numbers, ECoN, these calculated via Mean Fictive Ionic Radii, MEFIR, are calculated and disscussed.

Harvard Citation style: FISCHER, D. and HOPPE, R. (1992) THE 1ST LITHOMANGANATE(V) WITH LAYER-STRUCTURE - CS2(LI[MNO4]), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 618(12), pp. 59-62

APA Citation style: FISCHER, D., & HOPPE, R. (1992). THE 1ST LITHOMANGANATE(V) WITH LAYER-STRUCTURE - CS2(LI[MNO4]). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 618(12), 59-62.