Journal article

Publication year: 1992

Pages: 303-320

Journal: Journal of Organometallic Chemistry

Volume number: 434

Issue number: 3

ISSN: 0022-328X

DOI Link: https://doi.org/10.1016/0022-328X(92)83367-Q

Publisher: Elsevier

Abstract: 
The synthesis of the molybdenum allyl complexes Tp*Mo(CO)2(eta-3-crotyl) (2), TpMo(CO)2(eta-3-cyclohexenyl) (3a), Tp*Mo(CO)2(eta-3-cyclohexenyl) (3b), TpMo(CO)2(eta-3-cycloheptenyl) (4) and Tp*Mo(CO)2(eta-3-cyclooctenyl) (5) is described. The cyclic complexes 3 and 4 are converted to the cationic molybdenum dien complexes [TpMo(CO)2(eta-4-cyclohexadien))]+PF6- (7) upon treatment with Ph3CPF6. Complexes 6 and 7 react stereoselectively from the non-metal side with a braod range of nucleophiles. The crystal structure data analysis of 4 is discussed.

Harvard Citation style: IPAKTSCHI, J., HARTMANN, A. and BOESE, R. (1992) SYNTHESIS AND STEREOCONTROLLED FUNCTIONALIZATION OF HYDRIDOTRISPYRAZOLYL BORATE MOLYBDENUM DIENE COMPLEXES, Journal of Organometallic Chemistry, 434(3), pp. 303-320. https://doi.org/10.1016/0022-328X(92)83367-Q

APA Citation style: IPAKTSCHI, J., HARTMANN, A., & BOESE, R. (1992). SYNTHESIS AND STEREOCONTROLLED FUNCTIONALIZATION OF HYDRIDOTRISPYRAZOLYL BORATE MOLYBDENUM DIENE COMPLEXES. Journal of Organometallic Chemistry. 434(3), 303-320. https://doi.org/10.1016/0022-328X(92)83367-Q