Journal article

Publication year: 1992

Pages: 287-302

Journal: Journal of Organometallic Chemistry

Volume number: 434

Issue number: 3

ISSN: 0022-328X

DOI Link: https://doi.org/10.1016/0022-328X(92)83366-P

Publisher: Elsevier

Abstract: 
The reaction of TiCl4 with (C6H5)2P(CH2CH2O)nH (2) and K[(Pz*)3BH] affords the complexes Tp*TiCl2(OCH2CH2)nP(C6H5)2 (n = 1-3) (3), Tp*TiCl[(OCH2CH2)nP(C6H5)2]2 (n = 1-3) (4) and Tp*Ti[(OCH2CH2)nP(C6H5)2]3 (n = 1-3) (5) which are then converted into the heterobinuclear complexes 8 and 9. Similarly, we succeeded in the synthesis of the heterobimetallacycles Tp*TiCl[OCH2CH2P(C6H5)2]2Mo(CO)4 (13) and Tp*TiC][OCH2P(C6H5)2]2Mo(CO)4 (14) by the use of (CO)4Mo[P(C6H5)2CH2OH]2 (10) and (CO)4Mo[P(C6H5)2(CH2CH2O)nH]2 (n = 1-2) (11). The shortest distance between Ti and Mo according to the crystal structure analysis is 5.393 angstrom.

Harvard Citation style: IPAKTSCHI, J. and SULZBACH, W. (1992) SYNTHESIS AND CHARACTERIZATION OF HYDRIDOTRISPYRAZOLYL BORATE HETEROBIMETAL COMPLEXES WITH TITANIUM MOLYBDENUM, Journal of Organometallic Chemistry, 434(3), pp. 287-302. https://doi.org/10.1016/0022-328X(92)83366-P

APA Citation style: IPAKTSCHI, J., & SULZBACH, W. (1992). SYNTHESIS AND CHARACTERIZATION OF HYDRIDOTRISPYRAZOLYL BORATE HETEROBIMETAL COMPLEXES WITH TITANIUM MOLYBDENUM. Journal of Organometallic Chemistry. 434(3), 287-302. https://doi.org/10.1016/0022-328X(92)83366-P