Journal article

Publication year: 1992

Pages: 143-148

Journal: Journal of Inorganic and General Chemistry

Volume number: 612

Issue number: 6

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19926120124

Publisher: Wiley

Abstract: 
The compound that has been described as Cs4PbO3 really is Cs4PbO4. It does not crystallize in the space group P2(1), as assumed, but in P2(1)/c. The observed fictitiuos violation of the extinction law for the c glide plane is due to twinning. The structure was refined using the original data as well as new data from an untwinned crystal. The denomination beta-Cs4PbO4 is used to distinguish this structure from another known modification (alpha-Cs4PbO4). Both structures, alpha-Cs4PbO4 and beta-Cs4PbO4, can be derived from the sphere packing of gamma-plutonium when Certain voids in its packing are occupied with oxygen atoms.

Harvard Citation style: MULLER, U., BERNET, K. and HOPPE, R. (1992) CORRECTION OF THE CRYSTAL-STRUCTURE OF CS4PBO3 AND THE STRUCTURAL RELATIONSHIP BETWEEN THE MODIFICATIONS OF CS4PBO4, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 612(6), pp. 143-148. https://doi.org/10.1002/zaac.19926120124

APA Citation style: MULLER, U., BERNET, K., & HOPPE, R. (1992). CORRECTION OF THE CRYSTAL-STRUCTURE OF CS4PBO3 AND THE STRUCTURAL RELATIONSHIP BETWEEN THE MODIFICATIONS OF CS4PBO4. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 612(6), 143-148. https://doi.org/10.1002/zaac.19926120124