Journal article

Publication year: 1992

Pages: 89-96

Journal: Journal of Inorganic and General Chemistry

Volume number: 612

Issue number: 6

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19926120115

Publisher: Wiley

Abstract: 

By "reaction with the wall" we obtained for the first time transparent brown single crystals of Na4[AuCoO5] while heating intimate mixtures of Co3O4, Na2O2, and K2O2 (Co: Na: K = 1.00: 4.91:2.20; 650-degrees-C/44 d) in a sealed gold-tube: monoclinic, P 2(1)/m, with a = 555.69(4)pm, b = 1042.11(8) pm, c 555.69(4) pm, beta = 117.387(5)-degrees, Z = 2.

Characteristic features of Na4[AuCoO5] are meandric chains infinity1[(O2/2(CoO)O2AuO2/2)2].

The structure has been determined by four-circle diffractometer data (Siemens AED 2; Mo-K-alphaBAR, graphite, 881 I(o)(hkl), R = 0.0366, R(w) = 0.0316), parameters as given in the text. The Madelung Part of Lattice Energy, MAPLE, Effective Coordination Numbers, these via Mean Fictive Ionic Radii, and Charge-distribution, CHARDI, are calculated and discussed.

Harvard Citation style: MADER, K. and HOPPE, R. (1992) NOVEL MEANDER WITH CO-3+ AND AU-3+ - NA4[AUCOO5 = NA8 INFINITY-1 [(O2/2(COO)O2AUO2/2)2], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 612(6), pp. 89-96. https://doi.org/10.1002/zaac.19926120115

APA Citation style: MADER, K., & HOPPE, R. (1992). NOVEL MEANDER WITH CO-3+ AND AU-3+ - NA4[AUCOO5 = NA8 INFINITY-1 [(O2/2(COO)O2AUO2/2)2]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 612(6), 89-96. https://doi.org/10.1002/zaac.19926120115