Journalartikel

Jahr der Veröffentlichung: 1991

Seiten: 43-50

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 605

Heftnummer: 14

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19916050105

Verlag: Wiley

Abstract: 
By heating of a well-ground mixture of the binary oxides CsO0.55, Li2O and GeO2 (Cs:Li:Ge = 2,6:2,2:1; Ni-tube; 600-degrees-C; 49 d) we got single crystals of Cs2Li2[GeO4] for the first time. Cs2Li2[GeO4] is isotypic to Rb2Li2[MO4] (M = Si, Ti, Ge] [2] and Cs2Li2[MO4] (M = Si, Ti) [3]: according to this Cs2Li2[GeO4] crystallizes triclinic, in the spacegroup P1BAR with a = 968.7(4) pm, b = 586.0(2) pm, c = 571.4(2) pm, alpha = 92.71(4)-degrees, beta = 110.95(3)-degrees and gamma = 94.34(4)-degrees (Guinier-Simon data), Z = 2. The structure was determined by four-circle diffractometer data (Ag-K-alpha-; 2381 I(o)(hkl); R = 8,4%; R(w) = 5.0%), parameters see text. Further the Madelung Part of Lattice Energy (MAPLE), Effective Coordination Numbers (ECoN) and the Mean Fictive Ionic Radii (MEFIR), have been calculated.

Harvard-Zitierstil: HOFMANN, J. and HOPPE, R. (1991) ABOUT CS2LI2[GEO4], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 605(14), pp. 43-50. https://doi.org/10.1002/zaac.19916050105

APA-Zitierstil: HOFMANN, J., & HOPPE, R. (1991). ABOUT CS2LI2[GEO4]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 605(14), 43-50. https://doi.org/10.1002/zaac.19916050105