Journal article

Publication year: 1990

Pages: 87-94

Journal: Journal of Inorganic and General Chemistry

Volume number: 591

Issue number: 12

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19905910110

Publisher: Wiley

Abstract: 

By heating of well ground mixtures of the oxides [Cs2O2, RuO2, Cs:Ru = 2.2:1, Pd-tube, 800-degrees-C, 31 d] dark-green orthorhombic single crystals of Cs2RuO4 have been prepared for the first time: space group Pnma (No. 62); a = 851.20(11), b = 647.50(11), c = 1145.75(17) pm, is isostructural to beta-K2SO4.

The structure was determined by four-circle diffractometer data [MoK-alphaBAR, 977 from 984 I(o)(hkl), R = 5.8%, R(W) = 2.8%], parameters see text. The Madelung Part of Lattice Energy, MAPLE, the Effective Coordination Numbers, ECoN and the charge distribution have been calculated and discussed.

Harvard Citation style: FISCHER, D. and HOPPE, R. (1990) ON THE CONSTITUTION OF OXORUTHENATES(VI) .1. ON THE STRUCTURE OF CS2[RUO4], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 591(12), pp. 87-94. https://doi.org/10.1002/zaac.19905910110

APA Citation style: FISCHER, D., & HOPPE, R. (1990). ON THE CONSTITUTION OF OXORUTHENATES(VI) .1. ON THE STRUCTURE OF CS2[RUO4]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 591(12), 87-94. https://doi.org/10.1002/zaac.19905910110