Journal article

Publication year: 1990

Pages: 7-17

Journal: Journal of Inorganic and General Chemistry

Volume number: 590

Issue number: 11

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19905900102

Publisher: Wiley

Abstract: 

By heating of well ground mixtures of the oxides [Na2O2 and LiMnO4, Na:Mn = 2.8:1, Ag-tube, 580-degrees-C, 30 d] blue-green, orthorhombic single crystals of Na10{Li2[MnO4]4} have been prepared the first time. The structure determination (four circle diffractometer, MoK-alphaBAR, 2450 of 2469 I(o)(hkl), R = 8.6%, R(w) = 3.6%) confirms the space group Pnma (No. 62); a = 1048,1(7), b = 1518.4(9), c = 1044.4(6) pm.

Essential part of the structure are hitherto unknown connections of [MnO4] and [LiO4] groups to linear chains, which consist of six- and eight-membered rings out of O-Li-O-Mn-O. The structure is described via Schlegel diagrams. The Madelung Part of Lattice Energy. MAPLE, the Effective Coordination Numbers, ECoN, and the charge distribution have been calculated and discussed.

Harvard Citation style: FISCHER, D. and HOPPE, R. (1990) THE 1ST OXOMANGANATE(V) WITH CHAINS CONSISTING OF 6 AND 8 MEMBERED RINGS - NA10(LI2[MNO4]4), Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 590(11), pp. 7-17. https://doi.org/10.1002/zaac.19905900102

APA Citation style: FISCHER, D., & HOPPE, R. (1990). THE 1ST OXOMANGANATE(V) WITH CHAINS CONSISTING OF 6 AND 8 MEMBERED RINGS - NA10(LI2[MNO4]4). Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 590(11), 7-17. https://doi.org/10.1002/zaac.19905900102