Journal article

Publication year: 1977

Pages: 981-984

Journal: Hoppe-Seyler's Zeitschrift für physiologische Chemie

Volume number: 358

Issue number: 8

ISSN: 0018-4888

DOI Link: https://doi.org/10.1515/bchm2.1977.358.2.981

Publisher: De Gruyter

Abstract: 
The general validity of the Polonovski reaction with sulfonyl chlorides is demonstrated by the reaction of bansyl chloride and dansyl chloride with pseudotropine-N-oxide and the isomeric tropine-N-oxides yielding the corresponding N-Bansyl derivatives and N-Dansyl derivatives of the noralkaloids. The consequence of this reaction for the analytical determination of secondary amino derivatives with bansyl chloride, dansyl chloride and corresponding fluorophors is that secondary amino derivatives cannot be determined in the presence of the N-oxides of these amino derivatives.

Harvard Citation style: WIECHMANN, M. (1977) SCOPE AND LIMITATIONS OF ANALYTICAL USE OF DANSYL CHLORIDE .2. FORMATION OF SECONDARY DANSYL AMINES BY REACTION OF DANSYL CHLORIDE WITH N-OXIDES OF ALIPHATIC TERTIARY AMINO DERIVATIVES ACCORDING TO POLONOVSKI REACTION, Hoppe-Seyler's Zeitschrift für physiologische Chemie, 358(8), pp. 981-984. https://doi.org/10.1515/bchm2.1977.358.2.981

APA Citation style: WIECHMANN, M. (1977). SCOPE AND LIMITATIONS OF ANALYTICAL USE OF DANSYL CHLORIDE .2. FORMATION OF SECONDARY DANSYL AMINES BY REACTION OF DANSYL CHLORIDE WITH N-OXIDES OF ALIPHATIC TERTIARY AMINO DERIVATIVES ACCORDING TO POLONOVSKI REACTION. Hoppe-Seyler's Zeitschrift für physiologische Chemie. 358(8), 981-984. https://doi.org/10.1515/bchm2.1977.358.2.981