Journalartikel

Jahr der Veröffentlichung: 2018

Seiten: 8665-8672

Zeitschrift: Chemical Science

Bandnummer: 9

Heftnummer: 46

ISSN: 2041-6520

Open Access Status: Gold

DOI Link: https://doi.org/10.1039/c8sc03379j

Verlag: Royal Society of Chemistry

Abstract: 
A small single molecule with multiple photoswitchable subunits, selectively and independently controllable by light of different wavelengths, is highly attractive for applications in multi-responsive materials and biological sciences. Herein, triple photoswitches are presented consisting of three independent azobenzene (AB) subunits that share a common central phenyl ring: the meta-trisazobenzenes (MTA). It is the unique meta-connectivity pattern leading to decoupling of all azo-subunits although they do overlap spatially. Based on this pattern, we design a triple MTA photoswitch, as proof-of-principle, with three different, electronically independent AB branches on the computer, which can be individually photo-excited to trigger ultra-fast E -> Z isomerization at the selected AB branch.

Harvard-Zitierstil: Yang, C., Slavov, C., Wegner, H., Wachtveitl, J. and Dreuw, A. (2018) Computational design of a molecular triple photoswitch for wavelength-selective control, Chemical Science, 9(46), pp. 8665-8672. https://doi.org/10.1039/c8sc03379j

APA-Zitierstil: Yang, C., Slavov, C., Wegner, H., Wachtveitl, J., & Dreuw, A. (2018). Computational design of a molecular triple photoswitch for wavelength-selective control. Chemical Science. 9(46), 8665-8672. https://doi.org/10.1039/c8sc03379j