Journal article

Publication year: 2017

Pages: 26163-26171

Journal: Journal of Physical Chemistry C

Volume number: 121

Issue number: 47

ISSN: 1932-7447

DOI Link: https://doi.org/10.1021/acs.jpcc.7b06363

Publisher: American Chemical Society

Abstract: 
Two major strategies are currently pursued to improve the energy density of lithium-ion batteries using LiNixCoyMnzO2 (NCM) cathode materials. One is, to increase the fraction of redox active Ni (>= 80%), which allows larger amounts of Li to be extracted at a given cutoff voltage (U-max). The other is to increase U-max, in particular for medium-Ni content NCM materials. However, the accompanying lattice changes ultimately lead to capacity fading in both cases. Here the structural changes occurring in Li1.02NixCoyMnzO2 (with x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) during cycling operation in the voltage range between 3.0 and 4.6 V vs Li are quantified by means of operando X-ray diffraction combined with detailed Rietveld analysis. All samples show a large decrease in unit cell volume upon charging, ranging from 2.4% for NCM111 (33% Ni) to 8.0% for NCM851005 (85% Ni). To make a fair comparison of the structural stability of the different NCM materials, energy densities as a function of U-max are estimated and correlated with X-ray diffraction results. It is shown that NCMs with a lower Ni content allow for specific energies similar to that of, e.g., Ni-rich NCM811 (80% Ni) when operated at sufficiently high U-max, but still undergo less pronounced changes in structure. Nevertheless, as indicated by charge/discharge tests, the capacity retention of low- and medium-Ni content NCMs cycled to high U-max is also strongly affected by factors other than stability of the layered crystal lattice (electrolyte decomposition etc.). Overall, it is demonstrated that the complexity of the degradation processes needs to be better understood to identify optimal cycling conditions for specific cathode composition.

Harvard Citation style: de Biasi, L., Kondrakov, A., Gesswein, H., Brezesinski, T., Hartmann, P. and Janek, J. (2017) Between Scylla and Charybdis: Balancing Among Structural Stability and Energy Density of Layered NCM Cathode Materials for Advanced Lithium-Ion Batteries, Journal of Physical Chemistry C, 121(47), pp. 26163-26171. https://doi.org/10.1021/acs.jpcc.7b06363

APA Citation style: de Biasi, L., Kondrakov, A., Gesswein, H., Brezesinski, T., Hartmann, P., & Janek, J. (2017). Between Scylla and Charybdis: Balancing Among Structural Stability and Energy Density of Layered NCM Cathode Materials for Advanced Lithium-Ion Batteries. Journal of Physical Chemistry C. 121(47), 26163-26171. https://doi.org/10.1021/acs.jpcc.7b06363