Journalartikel

Jahr der Veröffentlichung: 2017

Seiten: 4806-4809

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 56

Heftnummer: 17

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.201701084

Verlag: Wiley

Abstract: 
Li47B3P14N42, the first lithium nitridoborophosphate, is synthesized by two different routes using a Li3N flux enabling a complete structure determination by single-crystal X-ray diffraction data. Li47B3P14N42 comprises three different complex anions: a cyclic [P3N9](12-), an adamantane-like [P4N10](10-), and the novel anion [P3B3N13](15-). [P3B3N13](15-) is the first species with condensed B/N and P/N substructures. Rietveld refinement, Li-6, Li-7, B-11, and P-31 solid-state NMR spectroscopy, FTIR spectroscopy, EDX measurements, and elemental analyses correspond well with the structure model from single-crystal XRD. To confirm the mobility of Li+ ions, their possible migration pathways were evaluated and the temperature-dependent conductivity was determined by impedance spectroscopy. With the Li3N flux route we gained access to a new class of lithium nitridoborophosphates, which could have a great potential for unprecedented anion topologies with interesting properties.

Harvard-Zitierstil: Bertschler, E., Bräuniger, T., Dietrich, C., Janek, J. and Schnick, W. (2017) Li47B3P14N42 - A Lithium Nitridoborophosphate with [P3N9](12-), [P4N10](10-), and the Unprecedented [B3P3N13](15-) Ion, Angewandte Chemie International Edition, 56(17), pp. 4806-4809. https://doi.org/10.1002/anie.201701084

APA-Zitierstil: Bertschler, E., Bräuniger, T., Dietrich, C., Janek, J., & Schnick, W. (2017). Li47B3P14N42 - A Lithium Nitridoborophosphate with [P3N9](12-), [P4N10](10-), and the Unprecedented [B3P3N13](15-) Ion. Angewandte Chemie International Edition. 56(17), 4806-4809. https://doi.org/10.1002/anie.201701084