Journalartikel
Autorenliste: Shubina, T.E.; Gunchenko, P.A.; Vigovskaya, T.S.; Schreiner, P.R.; Yurchenko, A.G.; Fokin, A.A.
Jahr der Veröffentlichung: 2002
Seiten: 229-236
Zeitschrift: Theoretical and Experimental Chemistry
Bandnummer: 38
Heftnummer: 4
DOI Link: https://doi.org/10.1023/A:1020511730749
Verlag: Springer
The structure of [3.3.2]- and [3.3.3]propellanes, their framework analogs, and their radical-cations was investigated by computational methods (BLYP and B3LYP) in the 6-31G* basis set. The reactivity of the propellanes toward model oxidizing electrophiles does not contradict the quantum-chemical calculations. In the case of the tetracyclic framework analog of [3.3.3]propellane the reaction takes place as C—H substitution, whereas in the case of [3.3.2]propellanes it takes place as C—C-oxidative addition.
Abstract:
Zitierstile
Harvard-Zitierstil: Shubina, T., Gunchenko, P., Vigovskaya, T., Schreiner, P., Yurchenko, A. and Fokin, A. (2002) [3.3.2]- and [3.3.3]Propellanes in Reactions with Oxidizing Electrophiles, Theoretical and Experimental Chemistry, 38(4), pp. 229-236. https://doi.org/10.1023/A:1020511730749
APA-Zitierstil: Shubina, T., Gunchenko, P., Vigovskaya, T., Schreiner, P., Yurchenko, A., & Fokin, A. (2002). [3.3.2]- and [3.3.3]Propellanes in Reactions with Oxidizing Electrophiles. Theoretical and Experimental Chemistry. 38(4), 229-236. https://doi.org/10.1023/A:1020511730749
