Journalartikel

Jahr der Veröffentlichung: 2019

Seiten: 5719-5723

Zeitschrift: Angewandte Chemie

Bandnummer: 131

Heftnummer: 17

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/ange.201901059

Verlag: Wiley

Abstract: 
With nearly 200 molecules detected in interstellar and circumstellar environments, the identification of the biologically relevant α‐keto carboxylic acid, glyoxylic acid (HCOCOOH), is still elusive. Herein, the formation of glyoxylic acid via cosmic‐ray driven, non‐equilibrium chemistry in polar interstellar ices of carbon monoxide (CO) and water (H2O) at 5 K via barrierless recombination of formyl (HCO) and hydroxycarbonyl radicals (HOCO) is reported. In temperature‐programmed desorption experiments, the subliming neutral molecules were selectively photoionized and identified based on the ionization energy and distinct mass‐to‐charge ratios in combination with isotopically labeled experiments exploiting reflectron time‐of‐flight mass spectrometry. These studies unravel a key reaction path to glyoxylic acid, an organic molecule formed in interstellar ices before subliming in star‐forming regions like SgrB2(N), thus providing a critical entry point to prebiotic organic synthesis.

Harvard-Zitierstil: Eckhardt, A., Bergantini, A., Singh, S., Schreiner, P. and Kaiser, R. (2019) Formation of Glyoxylic Acid in Interstellar Ices: A Key Entry Point for Prebiotic Chemistry, Angewandte Chemie, 131(17), pp. 5719-5723. https://doi.org/10.1002/ange.201901059

APA-Zitierstil: Eckhardt, A., Bergantini, A., Singh, S., Schreiner, P., & Kaiser, R. (2019). Formation of Glyoxylic Acid in Interstellar Ices: A Key Entry Point for Prebiotic Chemistry. Angewandte Chemie. 131(17), 5719-5723. https://doi.org/10.1002/ange.201901059